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In a small bowl, combine chili powder, salt, brown sugar, garlic powder, cumin and cayenne pepper.
Top with peppers and onion and season with remaining seasoning mix.
Put the lid on and cook on low for 3-4 hours, or on high for 2 hours, until chicken reaches an internal temperature of 165F degrees.
(Nutrition information provided is an estimate and will vary based on cooking methods and brands of ingredients used.)